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Personally, id have to say the Rift Stalker Armor is my favorite. As a hunter all throughout bc and early wrath i used the two piece(which heals your pet for 15% of the damage dealt by the player) to solo hard mobs and even some instances. Plus, it just looks all around awesome!
I love Paladin tier 6. It's the first, and in my opinion still, the only set that actually fits a Paladin.
My favorite tier is the warlock tier 10 i just love the helm
I would say the Mage T7 Valorous Frostfire Garb. The hood, those crystals emanating from the shoulders, the color and elaborate design is what makes it my favorite!
I really enjoyed Sanctified Frost Witch's Regalia, Frost Witch Regalia, as it was the first full set I had acquired, loved the look of it, and the 4 piece set bonus made my life MUCH easier.
My favorite tier set would have to be the judgment set, mainly because I find it very open and refreshing on a nice Azrothian morning.
Warrior T5 or Priest T6.They look scary but in a good way !Face on your shoulders ? Spike on your head ? Yes please.
My favorite was the Warlock T2 Nemesis Raiment, because it actually looks like a warlock set. Today blizzard have run out of ideas to make sets for Warlock, so they make them look like a cursed chicken, or a sack with misplaced horns. The Nemesis Raiment shows what Warlocks are made of, dark magic with some crazy demon stuff! I remember when I got my Nemesis Skullcap from Onyxia, I almost began crying because of the awesomeness.
My favorite would have to be the season six warrior pvp set, Furious Gladiator's Battlegear. It was the first time I actually put in enough time and effort into pvp to get the whole set, so walking around in it felt awesome. Plus, the pvp sets at that point looked so much better than the pve sets. I don't need glowy flamy shoulders, I'm a warrior. Make me look like a walking tank and I'm happy.
I like the warriors Tier 11 set the best, because it looks so brutal! In my opinion it fits a warrior perfectly, armor hard as stone, and just waiting to charge into a battle completely fearless and fight till you die, or most likely, kill the enemy! :)
Hunter T11
Druid Tier 2. There's a moose on the loose! I carry the hat and shoulders with me, even now. Aww yeah.
I really like paladin T11, as it's really the first tier I've ever been able to work towards completing, as I only recently started playing WoW. It's such a great feeling, slowing getting more and more pieces of the tier! Can't wait for T12!
I absolutely love the Priest Tier 6 set: Vestments of Absolution. The halo is so fitting for the priest class, and it just went together really well with my favorite shoulders in the game. The robe art is really cool too, it all matches perfectly. The hooded helm gave it a sort of mysterious yet devout look to it all. Not to mention the kick butt bonuses, both 2 and 4. And last but not least I really liked how T6 had not only the usual helm, shoulder, chest, legs, and gloves, but it had boots belt and bracers, too. It just completed the picture.
As a paladin my favorite paladin set has always been Judgment Armor. I love the way it looks, I wish the other paladin sets were half this badass looking. Purple power rangers? Flaming geodudes? /facepalm