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I have to go with Tiert 6 paladin, the Lightbringer one. Is just Soo paladin xD, cause of the holy light, and all yellowness. And also, you get to look like Sig Nicious :p
I would have to say hunter tier 5, due to its amazing 15% healing to pets, its the perfect set to use for large scale boss farming to this day.
Mine would be Tier 10 Raid Set for Priest Healer, Crimson Acolyte's Raiment, because it was the first time I had gotten a char in full tier gear! Albiet it was after Tier 11 came out but I was still very proud of it! (Would have gone with Tier 11 but Cata was like a month away...) xD
Yeah it's generic, but who didn't love Tier 6 Paladin back in the day? The shiny glowy goodness than even High Lord Fordring farmed for! Alternate shiny shoulders with your libram and hammer? Check! Halo of Light? Check! Powerhouse justice bringer storming the Temple with this beauty of a set on? Check! Man, Blizzard need a cosmetic option, I'd wear it all the time. Cho'gall would just drop his loot at my feet if he saw me in pimped up Lightbringer, and Deathwing would be my personal mount and 2v2 arena buddy.Rogues? P'shaw, your liquid filled shoulders don't scare me, same goes for you hunters with your gazing eyes in your shoulders and helmet. I am the Lightbringer, and I shall cast forth thine mighty Nerfhammer to smash you 6 feet under!~KendrubbinEdit: Arcanite Ripper in my bags with T6? I am Sig Nicious!
My Favorite Tier is Tier 4
Love Shaman T5 for looking awesome; the Samus shoulders were a plus.EDIT: Although Healing Priest T12 is looking pretty sexy for giving my Disc Priest a lolwell that no one will ever use.
Paladin T2 Judgment Armor aka the Judgement Set. When I first started playing in BC I saw a Paladin standing in Stormwind with that set on + Thunderfury, I was so smitten with the armour set that I rolled a Blood Elf Paladin to roleplay and acquire the set for my self. Sadly I haven't been able to get the set but I won't give up on it!
Paladin T2. Best-looking armor in the game, to this day.
Tier 10 for the Death Knights was my favorite. I always loved the Lich King's armor and having DK armor that resembled it was so cool.
My all-time favorite is the Tier 1 Might set for warriors! I love the way the silvery spikes really convey power and menace, and the way the helm looked like a giant bear trap! I was super happy to see the new BoA tank plate modeled after this set so that my new goblin warrior could relive the Molten Core glory days. :)
Judgement tier 2 for paladin, because its like your heartless in bright clothing, paladins need that flare color =P