The tier five Shaman armor was my favorite armor ever. You were effectively covered in lava, and it was also the only tier that went with two awesome weapons at the time. My goal was to get full enhancement t5 and both of the Fists of Molten Fury, after that I was content with life.
My favourite Tier gear would have to be the current Shadow priest one. I love the little pools on my shoulders, lol.
I absolutely loved Tier 7 for the hunters, but my favorite over-all sets were what dropped from ICC.
My favorite is the shaman tier 10, with the spirit beast coming out of the shoulders, the ice hanging off of the helm and shoulders. It just fitted the shaman class perfectly and will always be my favorite set.
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anything but hunter tier 11. the dead fish helmets did not look cool :/
Hunters T2 is my favorite used to look like a suit made more for going to some feast then going to battle
http://www.wowhead.com/itemset=-72#.Shaman T8 looks amazing...I fell in love almost right away. <3 Ulduar!
Among all the sets I'd have to go way back to classic and say Paladin tier 2. I believe that it is one of the, if not the, best sets to be created to date because it fits so well, not just with looks and appearance, but the feel of a paladin, Blizzard honestly couldn't ever create another set for the Paladin that would ever feel so perfect. When I looked at the full Judgement set for the first time my jaw dropped not only for the simple fact of it being so well designed that it fit so well into the lore given to us about the class but what I thought of the class had changed. I saw this righteous, powerful, and wise warrior fighting for his people, without fear, regret, using all he knew to fight his cause. It was and still will forever be my favorite set for that reason alone.
Paladin tier 2 is my favorite set. The hood and shoulders and the colors make the set look so very zealous and awe-inspiring.
My favorite armor is the druid tier 3 raid set "Dreamwalker Raiment".Whenever I try to picture a a restoration druid they are always wearing that armor.The fact that the druids eyes glowed green was just awsome.